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Question

On valence bond theory the geometry of Ni(CO)4 is tetrahedral.

A
True
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B
False
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Solution

The correct option is A True
In Ni(CO)4, Ni is in zero oxidation state.
Outermost orbital of Ni
Here 3d has one empty sub-orbital. This is because of tetrahedral geometry and diamagnetic. Since Ni is in zero oxidation state.

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