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Question

One mole BaF2 is treated with two moles of H2SO4.To make the resulting mixture neutral, NaOH is added. Moles of NaOH required in this process is :

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Solution

BaF21mol+H2SO41molBaSO41mol+H2F21mol
Thus, unreacted H2SO4=1 mol
H2F2 formed =1 mol

H2SO41mol+2NaOH2molNa2SO4+2H2O

H2F21mol+2NaOH2molNa2F2+2H2O

Thus, total NaOH required by 1 mol H2F2 (formed) and 1 mol H2SO4 (unreacted) =4 mol.

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