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Question

Out of the following compounds, which has the maximum covalent character?

A
AlCl3
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B
AlI3
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C
MgI2
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D
NaI
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Solution

The correct option is A AlI3
According to Fajan's Rule, smaller cation, larger anion and high charge value favour covalent character. Due to minimum electronegativity and maximum polarization, AlI3 has maximum covalent character.

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