The correct option is B O2 and He
In adiabatic process, PVγ=constant
For a monoatomic gas, γ=Cp/Cv=1.67
For a diatomic gas. γ=1.4
since, γdiatomic<γmonoatomic, with increase in volume, decrease in pressure would be more monoatomic gas.
Therefore, graph 1 is for diatomic and graph 2 is for monoatomic.