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Question

Schottky defect is likely to be found in:

A
AgI
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B
NaCl
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C
ZnS
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D
ZnO
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Solution

The correct option is A NaCl
In Nacl the existence of two vacancies, one due to a missing Na+ ions and other due to a missing Cl ions in a crystal of NaCl is showing in figure. The crystal , as a whole remains neutral because the number of missing positive and negative ions is the same. Thus a Schottky defects consists of a pair of holes in the crystal structure.

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