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Ozonolysis of Aromatics

The addition ...

Question

The addition of $1$ equivalent of $D C l$ to $1, 3 -$ cyclohexadiene generates a mixture of products. Find out the total no. of products.

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Solution

Addition of $D C l$ will give $3$ products,
$A$ and $B$ from nucleophlic addition and $C$ from free radical addition reaction.

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Q. Assertion :Addition of one equivalent of

H C l

1, 3 - b u t e n e

80^{0} C

3 - c h l o r o - 1 - b u t e n e

as a major product. Reason:

3 - c h l o r o - 1 - b u t e n e

is a kinetically controlled product.

Q. The addition of HBr to 1-butene gives a mixture of products (I),(II) and (III):
The mixture consists of :

Q. Assertion :Addition of one equivalent of

H C l

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gives 3-chloro-1-butene as major product. Reason: 3-chloro-1-butene is a kinetically controlled product.

Read the above assertion and reason and choose the correct option regarding it.

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Which of the above chlorides is not likely to form at all?

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0^{o} C

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Ozonolysis of Aromatics

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