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Question

The complex studied by Werner had a composition corresponding to the formula PtCl4.2KCl. From electrical conductance measurements, he determined that each formula unit contained three ions. He also found that silver nitrate did not give a precipitate of AgCl with this complex. Write a formula for this complex that agrees with this information.

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Solution

Since AgCl precipitate is not formed with this complex, this implies that Cl ions are not free and are inside the coordination sphere.
Also, it contains 3 ions. Therefore, the possible formula of this complex is K2[PtCl6].

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