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Ionization Isomerism

The complexes...

Question

The complexes $[P t {C l}_{2} {({N H}_{3})}_{4}] {B r}_{2}$ and $[P t {B r}_{2} {({N H}_{3})}_{4}] {C l}_{2}$ are examples for isomerism:

A

Geometrical

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B

Optical

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C

Ionisation

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D

Linkage

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Solution

The correct option is C Ionisation
Ionisation Isomers are those isomers where the isomers can be thought of as occurring because of the formation of different ions in solution.

In $[P t C l_{2} (N H_{3})_{4}] B r_{2}, B r^{-}$ in solution and in another isomer $[P t B r_{2} (N H_{3})_{4}] C l_{2}, B r^{-}$ anion in solution are examples of ionisation isomers.
Hence, option $C$ is correct.

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Similar questions

Q. What type of isomerism is exhibited by the following pairs of compounds :
(i)

[P t {C l}_{2} {(N H_{3})}_{4}] {B r}_{2}

[P t {B r}_{2} {(N H_{3})}_{4}] {C l}_{2}

{[C r (S C N) {(H_{2} O)}_{5}]}^{2 +}

{[C r (N C S) {(H_{2} O)}_{5}]}^{2 +}

Q. Write the IUPAC names of the following coordination compounds:
(i)

[C r {({N H}_{3})}_{4} {(H_{2} O)}_{2}] {C l}_{3}

[P t {C l}_{2} {({N H}_{3})}_{4}] [P t {C l}_{4}]

Q. In the complex

{[N i {(H_{2} O)}_{2} {(N H_{3})}_{4}]}^{+ 2}

the magnetic moment

(μ)

N i

Q. The complexes,

[P t C l_{2} {(N H_{3})}_{4}] B r_{2}

[P t B r_{2} {(N H_{3})}_{4}] C l_{2}

Q. The complexes

[C o (N O_{2}) {(N H_{3})}_{5}] {C l}_{2}

[C o (O N O) {(N H_{3})}_{5}] {C l}_{2}

are the examples of :

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