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Ionization Isomerism

The complexes...

Question

The complexes, $[P t C l_{2} {(N H_{3})}_{4}] B r_{2}$ and $[P t B r_{2} {(N H_{3})}_{4}] C l_{2}$ are:

A

geometrical isomers

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B

linkage isomers

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C

ionisation isomers

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D

co-ordination isomers

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Solution

The correct option is C ionisation isomers
$[P t C l_{2} {(N H_{3})}_{4}] B r_{2}$ and $[P t B r_{2} {(N H_{3})}_{4}] C l_{2}$ are ionisation isomers as they dissociate in solution to provide different ions.

$[P t C l_{2} {(N H_{3})}_{4}] B r_{2} ⇌ {[P t C l_{2} {(N H_{3})}_{4}]}_{2}^{2 +} + 2 B r^{-}$

$[P t B r_{2} {(N H_{3})}_{4}] C l_{2} ⇌ {[P t B r_{2} {(N H_{3})}_{4}]}_{2}^{2 +} + 2 C l^{-}$

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Similar questions

Q. The compounds

[P t C l_{2} {(N H_{3})}_{4}] B r_{2}

[P t B r_{2} {(N H_{3})}_{4}] C l_{2}

constitute a pair of:

Q. Which one of the following pairs of isomers and types of isomerism are correctly matched?
(i)

[C o (N H_{3})_{5} (N O_{2})] C l_{2}

[C o (N H_{3})_{5} (O N O) C l_{2} . . . (L i n k a g e)

[C u (N H_{3})_{4}] [P t C l_{4}]

[P t (N H_{3})_{4}] [C u C l_{4}] . . . (C o o r d i n a t i o n)

[P t C l_{2} (N H_{3})_{4}] B r_{2}

[P t B r_{2} (N H_{3})_{4}] C l_{2} . . . (I o n i z a t i o n)

Select the correct answer using the codes given below:

Q. The complexes

[P t {C l}_{2} {({N H}_{3})}_{4}] {B r}_{2}

[P t {B r}_{2} {({N H}_{3})}_{4}] {C l}_{2}

are examples for isomerism:

Q. How many co-ordination isomers are possible for the following complex? (Including given isomer)

[C r (N H_{3})_{6}] [F e (C_{2} O_{4})_{3}]

[Pt(NH₃)₄Cl₂]Br₂ and [Pt(NH₃)₄Br₂]Cl₂ is a type of:

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