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Addition of Sulphuric Acid and Water

The compound ...

Question

The compound (A) having molecular formula C3H3Cl with alcoholic KOH gives compound (B) with mol formula C3H6 (B) compound with HBr undergoes addition reaction to form C. Identify A,B,C and explain the reactions

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Solution

$T h e f o r m u l a o f A i s C_{3} H_{7} C l . A u n d e r g o e s r e a c t i o n w i t h a l c o K O H g i v i n g c o m p o u n d B, s o B i s a n a l k e n e w h i c h i s c o n f i r m e d b y i t s f o r m u l a (C_{3} H_{6}) . S o A i s a n a l k y l h a l i d e . B u n d e r g o e s a d d i t i o n r e a c t i o n w i t h H B r, a c c o r d i n g t o M a r k o n i k o f f r u l e t o g i v e p r o d u c t C, w h e r e i s a n a l k y l b r o m i d e . T h e r e a c t i o n s a r e C H_{3} C H_{2} C H_{2} C l \to_{- H C l}^{a l c K O H} C H_{3} C H = C H_{2} \overset{H B r}{\to} C H_{3} C H (B r) C H_{3} A B C T h u s A = P r o p y l c h l o r i d e B = P r o p e n e C = 2 - B r o m o p r o p a n e$

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