The correct order of increasing basicity of the following is H2O,OH−,CH3OH,CH3O−:
A
CH3OH<H2O<OH−<CH3O−
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B
H2O<CH3OH<CH3O−<OH−
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C
H2O<CH3OH<OH−<CH3O−
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D
CH3OH<H2O<CH3O−<OH−
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Solution
The correct option is CH2O<CH3OH<OH−<CH3O− Basicity depends upon the availability of lone pair of electrons for donation. Between H2O and CH3OH, the later is more basic because of the presence of electron donating −CH3 group. Thus, CH3OH>H2O (basicity order) Conjugate base of weaker acid is strong. Thus, CH3O−>OH− (basicity order) Hence, the increasing order of basicity is CH3O−>OH−>CH3OH>H2O.