The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexes : CoCl3.6NH3,CoCl3.5NH3,CoCl3.4NH3 respectively is:
A
1AgCl,3AgCl,2AgCl
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B
3AgCl,1AgCl,2AgCl
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C
3AgCl,2AgCl,1AgCl
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D
2AgCl,3AgCl,1AgCl
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Solution
The correct option is C3AgCl,2AgCl,1AgCl [Co(NH3)6].Cl3+3AgNO3→3AgCl
[Co(NH3)5Cl].Cl2+2AgNO3→2AgCl
[Co(NH3)4Cl2].Cl+AgNO3→AgCl
Thus the correct order of stoichiometries of AgCl formed when AgNO3 is added in excess to the above mentioned complexes will be 3, 2 and 1.