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Question

The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexes : CoCl3.6NH3,CoCl3.5NH3,CoCl3.4NH3 respectively is:

A
1 AgCl, 3 AgCl, 2 AgCl
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B
3 AgCl, 1 AgCl, 2 AgCl
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C
3 AgCl, 2 AgCl, 1 AgCl
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D
2 AgCl, 3 AgCl, 1 AgCl
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Solution

The correct option is C 3 AgCl, 2 AgCl, 1 AgCl
[Co(NH3)6].Cl3 + 3AgNO3 3AgCl

[Co(NH3)5Cl].Cl2 + 2AgNO3 2AgCl

[Co(NH3)4Cl2].Cl + AgNO3 AgCl

Thus the correct order of stoichiometries of AgCl formed when AgNO3 is added in excess to the above mentioned complexes will be 3, 2 and 1.

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