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Question

The correct stability order for the following species is:
32366_6db0584e84034bec8e410e9eeeaa2e76.png

A
(II)>(IV)>(I)>(III)
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B
(I)>(II)>(III)>(IV)
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C
(II)>(I)>(IV)>(III)
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D
(I)>(III)>(II)>(IV)
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Solution

The correct option is D (I)>(III)>(II)>(IV)
The correct stability order for the following species is
I>III>II>IV

In Ist the lone pair on oxygen stabilises the carbocation as well as it is tertiary carbocation, hence more stable.

The correct order of the stability of carbocations is tert alkyl > sec alkyl > primaryalkyl > methyl carbonium ion.

When an electron donating group (+I effect) present, the stability of carbocation increases.

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