The dipole moment of LiF was experimentally determined and was found to be 6.32D. The percentage ionic character in LiF molecule is Li−F bond length is 0.156nm. (write the value to the nearest integer)
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Solution
Dipole moment assuming 100 % ionic character would be the product of its charge and the inter atomic distance.
It would be 4.8×10−10esu×1.56×10−8cm=7.48×10−18esu.cm=7.48D as 1D=1×10−18esucm Percent ionic character is the ratio of the observed dipole moment to the dipole moment assuming 100% ionic character. This ratio is multiplied by 100.