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Question

The dipole moment of LiF was experimentally determined and was found to be 6.32D. The percentage ionic character in LiF molecule is
LiF bond length is 0.156nm. (write the value to the nearest integer)

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Solution

Dipole moment assuming 100 % ionic character would be the product of its charge and the inter atomic distance.
It would be 4.8×1010esu×1.56×108cm=7.48×1018esu.cm=7.48D
as 1D=1×1018esucm
Percent ionic character is the ratio of the observed dipole moment to the dipole moment assuming 100% ionic character. This ratio is multiplied by 100.
Percent ionic character 6.327.48×100=84.35

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