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Question

The limiting molar conductivity and molar conductivity of acetic acid are 390.5 s.cm2.mol1 and 48.15 s.cm2.mol1 respectively. Calculate the degree of dissociation of the weak acid?

A
1.233
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B
12.33
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C
0.1233
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D
0.01233
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Solution

The correct option is C 0.1233
The degree of dissociation is give by the following relation:
α=ΛmΛ0
Where α is the degree of dissociation, Λm is the molar conductivity and Λ0 is the molar conductivity at infinite dilution i.e. limiting molar conductivity
on substitution we get:
α=48.15390.5
α=0.1233
option C is correct

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