The major product obtained by the addition reaction of HBr to 4-methylpent-1-ene in the presence of peroxide is:
A
1-bromo-4-methylpentane
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B
4-bromo-2-methylpentane
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C
2-bromo-4-methylpentane
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D
3-bromo-2-methylpentane
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Solution
The correct option is A 1-bromo-4-methylpentane In the presence of peroxide, addition of HBr to unsymmetrical alkenes takes place according to anti Markovnikov’s rule.