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Question

The order of basic strength among the following amines in benzene will be


A

CH3NH2 > (CH3)3 N > (CH3)2 NH

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B

(CH3)3 N > (CH3)2 NH > CH3 NH2

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C

CH3 NH2 > (CH3)2 NH > (CH3)3 N

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D

(CH3)2 NH > CH3 NH2 > (CH3)3 N

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Solution

The correct option is B

(CH3)3 N > (CH3)2 NH > CH3 NH2


In non-aqueous solvents tertiary amine is most basic as three alkyls group being + push the electron density towards nitrogen. nitrogen can donate lone pair of electrons more easily


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