The correct option is B HCOOH and CH3COOH
The pair of molecules which forms the strongest intermolecular hydrogen bonds is formic acid HCOOH, and acetic acid CH3COOH. A hydrogen bond is the electrostatic attraction between polar molecules that occurs when a hydrogen (H) atom bound to a highly electronegative atom such as nitrogen (N), oxygen (O) or fluorine (F) experiences attraction to some other nearby highly electronegative atom.