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Question

The product (s) via-oxymercuration (HgSO4+H2SO4) of 1-butyne would be:

A
CH3CH2O||CCH3
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B
CH3CH2CH2CHO
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C
CH3CH2CHO+HCHO
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D
CH3CH2COOH+HCOOH
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Solution

The correct option is A CH3CH2O||CCH3
OCH3CH2CCHHgSO4/H2SO4−−−−−−−−2H2OCH3CH2C(OH)2CH3H2O−−−CH3CH2CCH3
1-butyne on reaction with mercurous sulphide and sulphuric acid forms isobutyl alcohol as a product which undergoes tautomerism to form ethyl methyl ketone as a product.

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