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Question

The questions below are related to the manufacture of ammonia.
(a) Name the process.
(b) In what ratio must the reactants be taken?
(c) Name the catalyst used.
(d) Give the equation for the manufacture of ammonia.
(e) Ammonia can act as a reducing agent-write a relevant equation for such a reaction.


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Solution

Manufacture of Ammonia NH3 by Haber's Process:

  • In this process, a mixture of pure dry nitrogen N2 (obtained by fractional distillation of air) and hydrogen gas H2 in the ratio of 1:3 by volume is compressed to 200-500 atmospheric pressure.
  • The compressed gases are passed over heated catalyst of iron at a temperature of 450°C to 500°C.
  • N2+3H2Fe500°C,250atm2NH3+22,400cal

Reducing Action of Ammonia:

  • Ammonia is a strong reducing agent. It reduces metallic oxides and chlorine.
  • Ammonia reduces copper(II) oxide(CuO) into metallic copper.
  • 3CuO(s)+2NH3(g)3Cu(s)+3H2O(l)+N2(g)

  1. The process is Haber's process.
  2. The reactants must be taken in the ratio 1:3.
  3. Iron is used as catalyst.
  4. N2(g)+3H2(g)Fe500°C,250atm2NH3(g)+22,400cal
  5. 3CuO(s)+2NH3(g)3Cu(s)+3H2O(l)+N2(g)

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