The reactions of Cl2 gas with cold-dilute and hot-concentrated NaOH in water give sodium salts of two different oxoacids of chlorine, P and Q, respectively. The Cl2 gas reacts with SO2 gas, in presence of charcoal, to give a product R reacts with white phosphorus to give a compound S. On hydrolysis, S gives an oxoacid of phosphorus.
3. P and Q, respectively, are the sodium salts of
Hypochlorous and chloric acids
2NaOH+Cl2→NaCl+NaClO+H2O
(Cold + dil.) P
6NaOH+3Cl2→5NaCl+NaClO3+H2O
(Hot + conc.) Q