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Byju's Answer
Standard XIII
Chemistry
Factors Affecting CFSE and Conclusions
[TiH2O6]3+ ab...
Question
[
T
i
(
H
2
O
)
6
]
3
+
absorbs light of wavelength 498 nm during a d–d transition. The octahedral splitting energy for the above complex is
×
10
−
19
J
. (Round off to the nearest integer).
h
=
6.626
×
10
−
34
J s
; c = 3 \times 10^8~\text{ m s}^{-1}\).
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Solution
Δ
0
=
h
c
I
a
b
s
=
6.626
×
10
−
34
×
3
×
10
8
498
×
10
−
9
=
6.626
×
3
498
×
10
−
17
=
3.99
×
10
−
19
Nearest integer
=
4
×
10
−
19
J
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Similar questions
Q.
When light of wavelength
248
nm
falls on a metal of threshold energy
3.0
eV
, the de-Broglie wavelength of emitted electrons is
∘
A
. (Round off to the nearest Integer).
[
Use
:
√
3
=
1.73
;
h
=
6.63
×
10
−
34
J s
;
m
e
=
9.1
×
10
−
31
kg
;
c
=
3.0
×
10
8
m s
−
1
;
1
eV
=
1.6
×
10
−
19
J
]
Q.
[
T
i
(
N
C
S
)
6
]
3
−
ion exhibits a single absorption band at 544 nm. What will be the crystal field splitting energy (in kJ/mol) of the complex ?
(
h
=
6.626
×
10
−
34
J
s
;
c
=
3
×
10
8
m
/
s
;
N
A
=
6.02
×
10
23
i
o
n
s
/
m
o
l
e
)
Q.
Electromagnetic radiation of wavelength 663 nm is just sufficient to ionize the atom of metal A. The ionization energy of metal A in kJ mol
−
1
is
.
(Rounded off to the nearest integer)
[
h
=
6.63
×
10
−
34
Js
,
c
=
3.00
×
10
8
ms
−
1
,
N
A
=
6.02
×
10
23
mol
−
1
]
Q.
Calculate the energy of radiation emitted for the electronic transition from infinity to ground state for
L
i
2
+
ion.
(
Given
:
c
=
3
×
10
8
m/s
,
R
H
=
1.09678
×
10
7
m
−
1
h
=
6.626
×
10
−
34
J s
−
1
)
Q.
Calculate the energy in joule corresponding to light of wavelength 45 nm.
(Planck's constant
,
h
=
6.63
×
10
−
34
J
.
s
,
speed of light
,
c
=
3
×
10
8
m
.
s
−
1
)
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