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Question

[Ti(H2O)6]3+ absorbs light of wavelength 498 nm during a d–d transition. The octahedral splitting energy for the above complex is ×1019 J. (Round off to the nearest integer). h=6.626×1034 J s; c = 3 \times 10^8~\text{ m s}^{-1}\).

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Solution

Δ0=hcIabs=6.626×1034×3×108498×109
=6.626×3498×1017=3.99×1019
Nearest integer =4×1019 J

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