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Question

What amount of NaNO3 (in grams) that has a percentage purity of 30% produces 0.56 litre of O2 at STP (atm) on decomposition?
Given reaction: 2NaNO32NaNO2+O2

A
18.42 g
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B
14.16 g
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C
21.59 g
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D
7.13 g
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Solution

The correct option is B 14.16 g
As per the reaction: 2NaNO32NaNO2+O2

22.4 L of O2 is produced by decomposition of 2 moles of NaNO3
0.56 L of O2 is produced by 222.4×0.56=0.05 moles of NaNO3
Amount of pure NaNO3 decomposed =0.05 mol×85 (g/mol) = 4.25 g
But purity of sample = 30% (given)
Actual amount of NaNO3 required =4.2530×100=14.16 g

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