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Question

What will be the e.m.f of the given cell? Pt|H2(P1)|H+(aq)|H2(P2)|Pt

A
RTFPlnP1P2
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B
RT2FlnP1P2
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C
RTFlnP2P1
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D
none of these
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Solution

The correct option is B RT2FlnP1P2
H2(P1)+2H+(1M)2H+(1M)+H2(P2)
Ecell=E0cellRTnFIn
=0RT2FInP2P1 [for concentration cell, E0cell=0]
=RT2FInP1P2

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