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Representation of Cell

Pt| H 2 p 1 ...

Question

$P t | \frac{H_{2}}{(p_{1})} ∥ \frac{H^{+}}{(1 M)} ∥ \frac{H^{+}}{(1 M)} ∥ \frac{H_{2}}{(p_{2})} | P t$ (where $p_{1}$ and $p_{2}$ are pressure) cell reaction will be spontaneous if:

p_{1} = p_{2}

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p_{1} > p_{2}

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p_{2} > p_{1}

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p_{1} = 1 a t m

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Solution

The correct option is B $p_{1} > p_{2}$
$P t | H_{2} (P_{1}) | ∣ ∣ H^{+} (1 m) ∣ ∣ ∣ ∣ H^{+} (1 M) ∣ ∣ H_{2} (P_{2}) / P t$
$E_{c e l l} = \frac{0.059}{2} l o g (\frac{P_{a n o d e}}{P_{c a t h o d e}})$
$E_{c e l l} = \frac{0.059}{2} l o g (\frac{P_{1}}{P_{2}})$
for $E_{c e l l} > 0, l o g (\frac{P_{1}}{P_{2}}) > 0$
$∴ P_{1} > P_{2}$

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