When sodium sulphite reacts with the dilute hydrochloric acid, salt X, water and gas Y is formed. Gas X decolourised pink potassium permanganate solution. Gas X is:
SO2
When sodium sulphite reacts with the dilute hydrochloric acid, sodium chloride, water and sulphur dioxide gas is formed.
Na2SO3+2HCl→2NaCl+H2O+SO2
Sulphur dioxide gas is colourless with a smell of burning sulphur i.e., suffocating odour. It turns moist blue litmus red and finally bleaches it. It decolourises pink potassium permanganate solution.
2KMnO4Pink+2H2O+5SO2→K2SO4colourless+2MnSO4+2H2SO4