When strongly heated, orthoboric acid leaves a residue of:
Metaboric acid
Tetraboric acid
Boric anhydride
Boron
H3BO3 100oC−−−→ HBO2 + H2O
HBO2 160oC−−−→ H2B4O7 + H2O
H2B4O7 △−→ 2B2O3 + H2O
When orthoboric acid is heated to red heat the residue is