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Question

Which of the following compounds do not undergo aldol condenstion?

A
CH3CHO
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B
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C
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D
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Solution

The correct option is D
Aldol condensation

The aldehydes and ketones having at least two alpha hydrogens aH undergo aldol candensation.

Base catalysed aldol reaction:



Base catalysed Dehydation:


Analysing the options

Option (A)

Ethanal has three alpha hydrogens and thus will undergo aldol condensation.


Option (B)
In the compound ,no alpha hydrogen is present. Therefore, it will not undrego aldol condensation.


Option (C)

Acetone has six alpha hydrogens and thus will undergo condensation.


Option (D)

In this compound, no alpha hydrogen is present. Therefore, it will not undergo aldol condensation.


Hence, option B and D are the correct answers.

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