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Nucleophile

Which of the ...

Question

Which of the following compounds is likely to show both Frenkel and Schottky defects in its crystalline form ?

A

A g B r

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B

K B r

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C

C s C l

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D

Z n S

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Solution

The correct option is A $A g B r$
Solids like $Z n S, A g C l, A g B r & A g I$ shows Frenkel defects.
Solids like $N a C l, K C l, K B r, A g B r and C s C l$ shows Schottky defect.
Hence, $A g B r$ shows both, Frenkel as well as Schottky defects.

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Q. Which one of the following compounds show both Schottky and Frenkel defects?

K C l

is more likely to show the Schottky defect, while

L i

is more likely to show Frenkel defect. Reason: The schottky defect is found in those ionic solid which have cation and anion of similar size while Frenkel defect is more likely found in those solids which have the cation of smaller size.

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Statement 2: Schottky defect is more likely in ionic solids in which cations and anions are of comparable size while Frenkel defect is more likely is which cations and anions have large differences in their ionic sizes.

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