Which of the following is in order of increasing covalent character ?
A
CCl4<BeCl2<BCl3<LiCl
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B
LiCl<CCl4<BeCl2<BCl3
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C
LiCl<BeCl2<BCl3<CCl4
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D
LiCl<BeCl2<CCl4<BCl3
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Solution
The correct option is DLiCl<BeCl2<BCl3<CCl4
Here, we have a common anion Cl−.
Along the period from left to right, the metallic character decreases and hence the tendency to form ionic bond decreases due to increase in ionization enthalpy.
Therefore, the tendency to form covalent bond increases along the period.
Oder of increasing covalent character:LiCl<BeCl2<BCl3<CCl4