Which of the following is the correct order for bond energy for C−H bonds in these compounds?
A
Y > Z > X
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B
X > Z > Y
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C
X > Y > Z
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D
Z > X > Y
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Solution
The correct option is C X > Y > Z C−H bond energy ∝1Stability of free radical
Free radical formed from X is a primary free radical and is the least stable. Free radical formed from Y is a allylic free radical hence it is more stable than the free radical from X. Free radical formed from Z is a allylic free radical with extended conjugation and hence it is most stable free radical.
So, the order of stability of free radical: Z > Y > X Hence CH bond energy follow the same i.e., X > Y > Z