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Question

Which of the following is true regarding acidity of phenol?

A
It is a stronger acid than carbonic acid.
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B
It is a stronger acid than benzoic acid.
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C
It is a stronger acid than water.
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D
It is a stronger acid than benzene sulphonic acid.
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Solution

The correct option is C It is a stronger acid than water.
When a molecule of phenol loses a proton, it forms phenoxide ion which is stabilized by resonance as the negative charge is delocalized over the aromatic ring.
No such resonance is present when a water molecule loses a proton to form hydroxide ion.
Hence, phenol is more acidic than water.

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