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Question

Which of the following pairs represents linkage isomers?

A
[Cu(NH3)4][PtCl4] and [Pt(NH3)][CuCl4]
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B
[Pd(PPh3)2(NCS)2] and [Pd(PPh3)2(SCN)2]
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C
[CO(NH3)5NO3]SO4 and [CO(NH3)5SO4]NO3
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D
[PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2
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Solution

The correct option is A [Pd(PPh3)2(NCS)2] and [Pd(PPh3)2(SCN)2]
Linkage isomerism is shown by ambidient ligand like NCS and SCN.

It can be linked through N( or ) S
[Pd(PPh3)(NCS2)] and [Pd(PPh3)2(SCN)2]

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