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Linkage Isomerism

Which of the ...

Question

Which of the following pairs represents linkage isomers?

A

[C u (N H_{3})_{4}] [P t C l_{4}]

and

[P t (N H_{3})] [C u C l_{4}]

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B

[P d (P P h_{3})_{2} (N C S)_{2}]

and

[P d (P P h_{3})_{2} (S C N)_{2}]

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C

[C O (N H_{3})_{5} N O_{3}] S O_{4}

and

[C O (N H_{3})_{5} S O_{4}] N O_{3}

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D

[P t C l_{2} (N H_{3})_{4}] B r_{2}

and

[P t B r_{2} (N H_{3})_{4}] C l_{2}

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Solution

The correct option is A $[P d (P P h_{3})_{2} (N C S)_{2}]$ and $[P d (P P h_{3})_{2} (S C N)_{2}]$
Linkage isomerism is shown by ambidient ligand like $N C S$ and $S C N$ .

It can be linked through N( or ) S
$∴ [P d (P P h_{3}) (N C S_{2})]$ and $[P d (P P h_{3})_{2} (S C N)_{2}]$

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Similar questions

Q. Which one of the following pairs of isomers and types of isomerism are correctly matched?
(i)

[C o (N H_{3})_{5} (N O_{2})] C l_{2}

[C o (N H_{3})_{5} (O N O) C l_{2} . . . (L i n k a g e)

[C u (N H_{3})_{4}] [P t C l_{4}]

[P t (N H_{3})_{4}] [C u C l_{4}] . . . (C o o r d i n a t i o n)

[P t C l_{2} (N H_{3})_{4}] B r_{2}

[P t B r_{2} (N H_{3})_{4}] C l_{2} . . . (I o n i z a t i o n)

Select the correct answer using the codes given below:

Q. The compounds

[P t C l_{2} {(N H_{3})}_{4}] B r_{2}

[P t B r_{2} {(N H_{3})}_{4}] C l_{2}

constitute a pair of:

Q. The complexes,

[P t C l_{2} {(N H_{3})}_{4}] B r_{2}

[P t B r_{2} {(N H_{3})}_{4}] C l_{2}

[C o (N H_{3})_{5} (S O_{4})] B r

[C o (N H_{3})_{5} B r] S O_{4}

are linkage isomers.

Q. Name the types of isomerism shown by the following pairs of compounds:
(i)

[C u {(N H_{3})}_{4}] [P t {C l}_{4}]

[P t {(N H_{3})}_{4}] [C u {C l}_{4}]

{[C o {(P n)}_{2} {C l}_{2}]}^{+}

{[C o {(t n)}_{2} {C l}_{2}]}^{+}

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