Which of the following structures possesses a cross-conjugated system?
A
CH2=CH−CH=CH−CH2
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B
CH2=CH−C|=CH2CH3CH2
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C
CH2=CH−CH|−CH=CH2CH=CH2
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D
CH2=CH−C|=CH=CH2CH2
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Solution
The correct option is DCH2=CH−C|=CH=CH2CH2 From the given options, only the above compound has conjugations in 3 carbon chains. One conjugation is in the chain form C1 to C4, other two are in chains from C1 to C3 and C4 to C5′ respectively. Hence, it is cross- conjugated system.