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Question

Which one of the following reagents does not break the OH bond when reacted with alcohol?

A
Na
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B
CH3COOH
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C
CH3MgBr
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D
PCl5
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Solution

The correct option is D PCl5
Only PCl5 gives a substitution reaction with alcohol replacing the OH group with Cl atom.
ROH+PCl5RCl+POCl3+HCl

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