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Solution
The correct option is ACaSO4.12H2OPlasterofParis+32H2OWater⟶CaSO4.2H2OGypsum Plaster of Paris when reacts with water liberating heat through crystallization. Gypsum is produced by heating plaster of paris to about 150-degree Celsius. When the dry plaster of paris powder is mixed with water it reforms into gypsum. Depending upon the temperature gypsum converts to hemihydrate or anhydrous form.