Write the name, the structure and the magnetic behavior of each of the following complexes:
(i) $(P t (N H_{3}) C l (N O_{2})]$
(ii) $(C o (N H_{3})_{4} C l_{2}] C l$
(iii) $N i (C O)_{4}$

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Solution

I) $[P t (N H_{3} C l (N O_{2})]$
Aminechloridonitrito-n-platinum(II)
Structure is square planar.
Magnetic behavior: Paramagnetic

II) $[C O (N H_{3})_{4} C l_{2}] C l$
Tetraaminedichloridocobalt chloride(IiI)
Structure is octahedral.
Magnetic behavior: Paramagnetic

III) $N i (C O)_{4}$
Tetra carboxy nickel(0)
Structure is Tetrahedral.
Magnetic behavior: Diamagnetic

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Similar questions

Q. Write the name, the structure and the magnetic behavior of each one of the following complexes:
(i)

[P t (N H_{3}) C l (N O_{2})]

(ii)

[C o (N H_{3})_{4} C l_{2}] C l

(iii)

N i (C O)_{4}

(At. Nos.

C o = 27, N i = 28, P t = 78

)

Among $[N i (C o)_{4}], [N i C l_{4}]^{2 -}, [C o (N H_{3})_{4} C l_{2}] C l, N a_{2} [C o F_{6}]^{3 +}, N a_{2} O_{2} a n d C s O_{2},$ the total number of paramagnetic compounds is

Q. Write IUPAC name of the following complex compounds
(i)

[N i (C O)_{4}]

(ii)

K_{2} [H g I_{4}]

Q. (a) Give the name and structural formula of one member each of the following:
(i) alkane
(ii) alkene
(iii) alkyne
(iv) cycloalkane
(b) Give the common name of (i) ethyne, and (ii) ethene.
(c) Write the molecular formula and structure of benzene.

Q. Using IUPAC norms write the systematic names of the following:
(i)

[C o (N H_{3})_{6}] C l_{3}

(ii)

[P t (N H_{3})_{2} C l (N H_{2} C H_{3})] C l

(iii)

[T i (H_{2} O)_{6}]^{3 +}

(iv)

[C o (N H_{3})_{4} C l (N O_{2}] C l

(v)

[M n (H_{2} O)_{6}]^{2 +}

(vi)

[N i C l_{4}]^{2 -}

(vii)

[N i (N H_{3})_{6}] C l_{2}

(viii)

[C o (e n)_{3}]^{3 +}

(ix)

[N i (C O)_{4}]

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Write the name, the structure and the magnetic behavior of each of the following complexes:(i) (Pt(NH3)Cl(NO2)](ii) (Co(NH3)4Cl2]Cl(iii) Ni(CO)4

Write the name, the structure and the magnetic behavior of each of the following complexes:
(i) $(P t (N H_{3}) C l (N O_{2})]$
(ii) $(C o (N H_{3})_{4} C l_{2}] C l$
(iii) $N i (C O)_{4}$