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Question

An alkali metal A gives a compound B (molecular mass = 40) on reacting with water. The compound B gives a soluble compound C on treatment with aluminum oxide. Identify A, B, and C and give the reaction involved.


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Solution

Step 1: Alkali metals:

  • Alkali metals are those metals that have their last electron present in s subshell as ns1 .
  • Alkali metals in reaction with water produce hydroxide ions.

Step 2: Determination of Alkali metal:

  • When alkali metal reacts with water it produces hydroxide of molecular weight 40 . Then,M+O+H=40.
  • Now putting the actual atomic weights of the atoms we get M+16+1=40.
  • Thus the calculated atomic weight of the alkali metal is M=4017=23.
  • Thus, Alkali metal A is Sodium that has 11 atomic number.

Step 3: Reaction of Sodium with water:

  • When Sodium reacts with water, it forms Sodium hydroxideNaOH along with the liberation of hydrogen H2gas.
  • The chemical reaction can be depicted as:
  • 2Na(s)+2H2O(l)2NaOH(aq)+H2(g)
  • Thus, compound B is Sodium hydroxide NaOH.

Step 4: Reaction of Sodium hydroxide with Aluminum oxide:

  • When Sodium hydroxide reacts with Aluminium oxide, it forms Sodium aluminateNaAlO2 and waterH2O.
  • The chemical reaction is depicted as:
  • Al2O3(s)+2NaOH(aq)2NaAlO2(s)+H2O(l)
  • Thus, compound C is Sodium aluminateNaAlO2.

Thus, compounds A, B, and C are alkali metals, Sodium hydroxide, and Sodium aluminate respectively.


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