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Question

30 g of urea (M=60 g mol1) is dissolved in 846 g of water. Calculate the vapour pressure of water for this solution if vapour pressure of pure water at 298 K is 23.8 mm Hg.

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Solution

According to Raoult's law:

Psolution=PowaterXwater=23.8×4749=22.83 mm Hg

Note:
Xwater=nwaternurea+nwater=846/1830/60+846/18=472+47=4749

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