Xenon Oxyfluorides
Trending Questions
Q. Which of the following pairs of compounds are isoelectronic and isostructural?
- BeCl2, XeF2
- TeI2, XeF2
- IF−2, XeF2
- IF3, XeF2
Q. Under ambient conditions, the total number of gases released products in the final step of the reaction scheme shown below is
(IIT-JEE Advanced, 2014)
(IIT-JEE Advanced, 2014)
- 3
- 1
- 2
- 0
Q. The BCl3 is a planar molecule whereas NCl3 is pyramidal because:
- Nitrogen atom is smaller than boron atom
- BCl3 has no lone pair but NCl3 has a lone pair of electrons
- B−Cl bond is more polar than N−Cl bond
- N−Cl bond is more covalent than B−Cl bond
Q. Consider the following statements about P4O10 and select the incorrect one.
- One mole of it requires 6 moles of water for complete hydrolysis
- It is used as a dehydrating agent
- Each phosphorus is tetrahedrally bonded to 4 oxygen atoms
- It hydrolyses in water to form phosphorus acid
Q. Which of the following xenon compounds may not be obtained by hydrolysis of xenon fluorides?
- XeO2F2
- XeOF4
- XeO3
- XeO4
Q. Match the compounds given in column I with the hybridisation and shape given in column II and mark the correct option.
Column I Column II(A)XeF6(i)distorted octahedral(B)XeO3(ii)square planar(C)XeOF4(iii)pyramidal(D)XeF4(iv)Square pyramidal
Column I Column II(A)XeF6(i)distorted octahedral(B)XeO3(ii)square planar(C)XeOF4(iii)pyramidal(D)XeF4(iv)Square pyramidal
- a - (iv); b - (iii); c - (i); d - (ii)
- a - (iv); b - (i); c - (ii); d - (iii)
- a - (i); b - (iii); c - (iv); d - (ii)
- a - (i); b - (ii); c - (iv); d - (iii)
Q. Bismuth chloride on hydrolysis forms a white ppt of
- Bismuth hydroxide
- Bismuth oxide
- Bismuth oxy chloride
- Bismuth
Q. Which of the following species is not isostructural with SiCl4?
- NH+4
- SCl4
- SO2−4
- PO3−4
Q. The shape and geometry of XeF4 are respectively:
- Square planar and octahedral
- tetrahedral and pyramidal
- Square planar and trigonal bipyramidal
- See - saw and trigonal planar
Q. The shape of NH3 molecule is:
- tetrahedral
- triagonal planar
- trigonal pyramidal
- linear
Q. Which of the following can be termed as oxyfluorides of Xenon?
- XeOF2
- XeOF4
- OF2
- XeO2F2
Q. Under ambient conditions, the total number of gases released as products in the final step of the reaction scheme shown below is:
- 0
- 1
- 2
- 3
Q. Xenon Fluorides are best stored in quartz containers – True or False?
- True
- False
Q.
What inspired N. Bartllett for carrying out reaction between Xe and PtF6 ?
Q. Which of the following pairs of compounds has same number of valence electrons and also isostructural ?
- IF3, XeF2
- BeCl2, XeF2
- TeI2, XeF2
- IBr−2, XeF2
Q. Which of the following are true for radius ratio (r+r−)?
i) If it is between 0.732 and 0.414, then the coordination number is 6 and is octahedral.
ii) If it is above 0.732 and less than 1.00, then coordination number is 8 and is cubic.
iii) If it is between 0.225 and 0.155, then coordination number is 3 and is triangular.
iv) If it is between 0.732 and 0.878, then coordination number is 8 and cubic.
i) If it is between 0.732 and 0.414, then the coordination number is 6 and is octahedral.
ii) If it is above 0.732 and less than 1.00, then coordination number is 8 and is cubic.
iii) If it is between 0.225 and 0.155, then coordination number is 3 and is triangular.
iv) If it is between 0.732 and 0.878, then coordination number is 8 and cubic.
- i and ii
- i and iii
- i, ii, iii and iv
- iii, iv
Q. Which of the following is correct regarding xenon fluorides?
- They are readily hydrolysed even by traces of water
- They are formed based on Xe/F2 ratio
- They are powerful fluorinating agents
- All of the above
Q. Molecule obtained by sp3d2 hybridization has bond angle of
Q. What is the hybridisation state of xenon in XeOF4?
- sp3
- sp3d
- sp3d2
- sp3d3
Q. How many lone pairs are present in the structure of XeO2F2?
- 2
- 0
- 3
- 1
Q. In which of the following compounds, the Fluorine atoms are placed axially in a trigonal bipyramidal geometry?
- XeOF2
- XeOF4
- XeF2
- XeO2F2
Q.
Number of lone pairs of electrons present in XeF2 molecule is -
- 5
- 4
- 6
- 3
Q. XeF6 on hydrolysis gives :
- XeOF4
- XeO2F2
- XeO3
- XeO4
Q.
List - I | List - II |
a)Ar+N2X−CuBr−−−→HBr | 1)ArF |
b)Ar+N2X−HBF4−−−→Δ | 2)ArH |
c)Ar+N2X−C2H5OH−−−−−→ | 3)ArOH |
d)Ar+N2X−H2O−−→ | 4)ArBr |
- a−4, b−1, c−2, d−3
- a−1, b−2, c−3, d−4
- a−2, b−3, c−4, d−1
- a−3, b−4, c−1, d−2
Q. The shape and geometry of XeF4 are respectively:
- Square planar and octahedral
- tetrahedral and pyramidal
- Square planar and trigonal bipyramidal
- See - saw and trigonal planar
Q. Which of the following can be termed as oxyfluorides of Xenon?
Q. In which of the following compounds, the Fluorine atoms are placed axially in a trigonal bipyramidal geometry?
Q. Which of the following can be termed as oxyfluorides of Xenon?
Q. Match the following:
Column I Column IIa.POCl31.Oxyacid formed during hydrolysisundergoes a tautomeric changeb.SOF22.Oxidation state of the central atom doesnot change during hydrolysisc.XeOF43.Complete as well as partial hydrolysis ispossibled.H2S2O84.Hydrolysed product reacts with glass5.Hybridization of the central atom in thefinal product remains the same as thesubstrate on hydrolysis
Column I Column IIa.POCl31.Oxyacid formed during hydrolysisundergoes a tautomeric changeb.SOF22.Oxidation state of the central atom doesnot change during hydrolysisc.XeOF43.Complete as well as partial hydrolysis ispossibled.H2S2O84.Hydrolysed product reacts with glass5.Hybridization of the central atom in thefinal product remains the same as thesubstrate on hydrolysis
- a - 2, 5
b - 1, 2, 4, 5
c - 2, 3, 4
d - 2, 3, 5 - a - 2, 3, 4
b - 2, 3, 5
c - 2, 5
d - 1, 2, 4, 5 - a - 1, 2, 4, 5
b - 2, 5
c - 2, 3, 5
d - 2, 3, 4 - a - 2, 3, 5
b - 2, 3, 4
c - 1, 2, 4, 5
d - 2, 5
Q. A xenon compound ‘A’ upon partial hydrolysis gives XeO2F2. The number of lone pairs of electrons present in compound A is ______. (Round off to the Nearest Integer).