At the start the 100N force is just enough to overcome static friction so we can write:
Force=Static Friction
F=μsecN
where μs is the coefficient of static friction and N= Normal Reaction that in an horizontal case such this will be equal to the weight of the block, so N=mg.
We get:
F=μsec×mg
in numbers:
100=μsec×9.8×20
μs=100×20×9.8=0.51
When the movement starts, kinetic friction kicks in and we have that to have uniform motion we need acceleration equal to zero (constant velocity).
We use Newton Second Law: F=ma:
or in our case:
Force−Kinetic Friction=mass⋅acceleration
or
F−μkN=0 because acceleration has to be zero
F−μk×mg=0
in number
F−0.4×20×9.8=0
F=78.4N