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Question

An aqueous solution of X is added slowly to an aqueous solution of Y as shown in List I. The variation in conductivity of these reactions is given in List II. Match List I with List II and select the correct option using the code given below the lists:
List IList II(A) (C2H5)3N+CH3COOH(P) Initially conductivity decreases and then increases X Y(B) KI(0.1M)+AgNO3(0.01M)(Q) Initially conductivity decreases and then does not change much X Y(C) CH3COOH+KOH(R) Initially conductivity increases and then does not change much X Y(D) NaOH+HI(S) Initially conductivity does not change much and then increases X Y
Which of the following is the only correct combination?

A
A-R; B-S; C-Q; D-P
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B
A-S; B-R; C-Q; D-P
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C
A-Q; B-R; C-S; D-P
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D
A-P; B-S; C-R; D-Q
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Solution

The correct option is A A-R; B-S; C-Q; D-P
Solutions of strong electrolytes has good conductivity and solutions of weak electrolyte has poor conductivity.

(A) (C2H5)3N+CH3COOH
X Y
(R) Since a weak base is added to a weak acid, the conductivity increases due to formation of the salt triethylammonium acetate and then does not change much after neutralization.


(B) KI(0.1M)+AgNO3(0.01M)
X Y
(S) Due to the formation of solid AgI, the conductivity does not change much initially and once all the AgNO3 is consumed then conductivity increases due to the excess KI.


(C) CH3COOH+KOH
X Y
(Q) Since a weak acid is added to a strong base, the conductivity decreases due to the consumption of strong base initially and then does not change much after neutralization.


(D) NaOH+HI
X Y
(P) Since a strong base is added to an acid, the conductivity decreases due to the consumption of strong acid and then after neutralization it increases.

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