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Chlorides of Phosphorus

Cl2 gas on re...

Question

$C l_{2}$ gas on reaction with hot and concentrated $N a O H$ gives:
[0.77 Mark]

A

N a C l + N a O C l

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B

N a C l + N a C l O_{3}

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C

N a O C l + N a C l O_{3}

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D

N a C l + N a C l O_{4}

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Solution

The correct option is B $N a C l + N a C l O_{3}$
$3 C l_{2} + 6 N a O H (hot and conc.) \to 5 N a C l + N a C l O_{3} + 3 H_{2} O$

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Similar questions

The reactions of $C l_{2}$ gas with cold-dilute and hot-concentrated NaOH in water give sodium salts of two different oxoacids of chlorine, P and Q, respectively. The $C l_{2}$ gas reacts with $S O_{2}$ gas, in presence of charcoal, to give a product R reacts with white phosphorus to give a compound S. On hydrolysis, S gives an oxoacid of phosphorus.

3. P and Q, respectively, are the sodium salts of

Q. The reaction of

C l_{2}

gas with cold dilute and hot concentrated NaOH in water give sodium salt of two (different) oxoacids of chlorine P and Q respectively. The

C l_{2}

gas reacts with

S O_{2}

gas, in presence of charcoal to give a product R. R reacts with white phosphorous to give a compound S. On hydrolysis, S gives an oxoacid of phosphorous T.
R, S and T, respectively are:

The reactions of $C l_{2}$ gas with cold-dilute and hot-concentrated NaOH in water give sodium salts of two different oxoacids of chlorine, P and Q, respectively. The $C l_{2}$ gas reacts with $S O_{2}$ gas, in presence of charcoal, to give a product R reacts with white phosphorus to give a compound S. On hydrolysis, S gives an oxoacid of phosphorus.

3. P and Q, respectively, are the sodium salts of

Q. The reaction of

C l_{2}

gas with cold dilute and hot concentrated NaOH in water give sodium salt of two (different) oxoacids of chlorine P and Q respectively. The

C l_{2}

gas reacts with

S O_{2}

gas, in presence of charcoal to give a product R. R reacts with white phosphorous to give a compound S. On hydrolysis, S gives as oxoacid of phosphorous T.
P and Q, respectively, are the sodium salts of:

Q. Paragraph 2
The reactions of

C l_{2}

gas with cold-dilute and hot-concentrated NaOH in water give soduum salts fo two different oxoacids of chlorine, P and Q, respectively. The

C l_{2}

gas reacts with

S O_{2}

gas, in presence of charcoal, to give a product R reacts with white phosphorus to give a compound S. On hydrolysis, S gives an oxoacid of phosphorus.

4. R, S and T, respectively, are
(IIT-JEE, 2013)

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