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Standard XIII
Chemistry
Covalent Bond vs Ionic Bond
Do bonding mo...
Question
Do bonding molecular orbitals have nodes?
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Solution
Bonding molecular orbitals:
Bonding molecular orbitals are formed by the interaction of orbitals of the atoms with the same symmetry.
They are lower in energy than atomic orbitals of an atom hence they have higher stability.
Nodes are points or planes in orbitals where the electron density is zero.
Generally, the presence of electrons is observed in the most stable states.
Therefore, bonding molecular orbitals do not have nodes.
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According to MOT (Molecular Orbital Theory), the molecular orbitals are formed by mixing of atomic orbitals through LCAO (linear combination of atomic orbitals). The correct statement (s) about molecular orbitals is/are Statement (a) : bonding molecular orbitals are formed by addition of wave-functions of atomic orbitals of same phase Statement (b) : anti-bonding molecular orbitals do not take part in bond formation because they belong to inner shells Statement (d) : anti-bonding molecular orbitals provide stability to molecules while bonding molecular orbitals make the molecules unstable.
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