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Question

Express the relation among cell constant, resistance of the solution in the cell and conductivity of the solution. How is molar conductivity of a solution related to its conductivity?

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Solution

G=1R
K=G×G
Substitue the value of conductance in the above equation
K=1R×G
R=1G
Molar conductivity is defined as the conductivity of an electrolyte solution divided by the molar concentration of the electrolyte, and so measures the efficiency with which a given electrolyte conducts electricity in solution.
=K×V
G is conductance.
K is conductivity.
G is cell constant.
is molar conductivity.
GG=K
Where, G=conductance, G=cell constant, K = conductivity
G×12=KG=RK
Λm=k×1000CScm2mol1

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