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Question

How will you prove that Hydrochloric acid contains (i) hydrogen (ii) chlorine? Write equations for the reactions.

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Solution

We can prove that hydrochloric acid contains both hydrogen and chlorine by the following experiment.
Take a voltameter used for electrolysis of water, fitted with a platinum cathode and a graphite anode. Into the voltameter pour 4 molar HCl and pass direct current.

It is seen that a colourless gas is evolved at the cathode and a greenish gas is evolved at the anode. When a burning splinter is brought near a colourless gas, it bursts into flame thereby proving that it is hydrogen gas. When moist starch iodide paper is held in the greenish-yellow gas, it turns blue-black, thereby proving that the gas is chlorine.
2 H C l space rightwards arrow space H subscript 2 space plus C l subscript 2
This experiment proves that hydrochloric acid contains both hydrogen and chlorine.


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