Electrophilic Substitution Reactions of Haloarenes
In the reacti...
Question
In the reaction C7H83Cl2/Δ−−−−→XBr2/Fe−−−−→YZn/HCl−−−−−→Z.
The compound Z is :
A
o-bromotoluene
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B
m-bromotoluene
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C
p-bromotoluene
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D
3-bromo-2, 2, 6-trichlorotoluene
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Solution
The correct option is B m-bromotoluene Z is m-bromotoluene.
Toluene is heated with chlorine to form (trichloromethyl)benzene. The aromatic nucleus is then brominated with bromine in presence of iron to form 1-bromo-3-(trichloromethyl)benzene.
Treatment with Zn/HCl gives m-bromotoluene (compound Z).