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Question

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The reactions of Cl2 gas with cold-dilute and hot-concentrated NaOH in water give soduum salts fo two different oxoacids of chlorine, P and Q, respectively. The Cl2 gas reacts with SO2 gas, in presence of charcoal, to give a product R reacts with white phosphorus to give a compound S. On hydrolysis, S gives an oxoacid of phosphorus.

4. R, S and T, respectively, are
(IIT-JEE, 2013)

A
SO2Cl2,PCl5andH3PO4
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B
SO2Cl2,PCl3andH3PO3
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C
SOCl2,PCl3andH3PO2
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D
SOCl2,PCl5andH3PO4
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Solution

The correct option is A SO2Cl2,PCl5andH3PO4
SO2+Cl2CharcoalSO2Cl2
R
SO2Cl2+P4PCl5+SO2
S
PCl5+H2OH3PO4+HCl
T

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