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Question

The correct order of bond angles in OCl2, H2O and OF2 would be

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Solution

The O-X (where X = Cl, F, H) bond will have its bond pair closer to X when X is F, since F has higher electronegativity. So the electrons move towards F and the distance between them, as a consequence, decreases. And therefore the bp-bp repulsion decreases, leading to a decrease in bond angle. Whereas this effect is less pronounced in OCl2. `Whereas this effect applies to H2O as well but the value lies in between of OF2 and OCl2 Therefore, the bond angle in OF2<H2O<OCl2

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